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Chem 116 - General Chemistry II

Selective Precipitation II- Video Solution

Consider the solution of the previous problem containing three metal cations;

[Pb2+] = [Ag+] = [Hg22+ ] = 0.0015M.


We just determined that:


The PbCl2 system was at equilibrium when [Cl] = 0.11 M,


The AgCl system was at equilibrium when [Cl] = 1.2 X 10–7 M,


The Hg2Cl2 system was at equilibrium when [Cl] = 3.1 X 10–8M.


Questions:
What concentration of Cl ions is needed to precipitate all of the ions but Pb2+?


What is the concentration of Hg22+ ions in the solution at this concentration of Cl?

 



Video B51