Chem 116 - General Chemistry II

Chemistry Home
Selective Precipitation II- Video Solution
Consider the solution of the previous problem containing three metal cations;
[Pb2+] = [Ag+] = [Hg22+ ] = 0.0015M.
We just determined that:
The PbCl2 system was at equilibrium when [Cl–] = 0.11 M,
The AgCl system was at equilibrium when [Cl–] = 1.2 X 10–7 M,
The Hg2Cl2 system was at equilibrium when [Cl–] = 3.1 X 10–8M.
Questions:
What concentration of Cl– ions is needed to precipitate all of the ions but Pb2+?
What is the concentration of Hg22+ ions in the solution at this concentration of Cl–?
Video B51