Chem 116 - General Chemistry II

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Selective Precipitation I- Video Solution
Consider a solution containing three metal cations; [Pb2+] = [Ag+] = [Hg22+ ] = 0.0015M.
At what concentration of Cl–(aq) will each salt just begin to precipitate (be at equilibrium)?
Ksp of PbCl2 = 1.7×10-5 Ksp of AgCl = 1.8×10-10 Ksp of Hg2Cl2 = 1.4×10-18
What concentration of chloride ion must be present to precipitate as much of the Hg22+ (as Hg2Cl2) as possible without precipitating the chlorides of Ag+, and Pb2+?
Video B51