Chemistry Problem Solving Videos @ WVU

Chem 116 - General Chemistry II

Selective Precipitation I- Video Solution

Consider a solution containing three metal cations;    [Pb2+] = [Ag+] = [Hg22+ ] = 0.0015M. 

At what concentration of Cl(aq) will each salt just begin to precipitate (be at equilibrium)?

Ksp of PbCl2 = 1.7×10-5        Ksp of AgCl = 1.8×10-10      Ksp of Hg2Cl2 = 1.4×10-18   


What concentration of chloride ion must be present to precipitate as much of the Hg22+ (as Hg2Cl2) as possible without precipitating the chlorides of Ag+, and Pb2+?

 



Video B51