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Chem 116 - General Chemistry II

Reaction Mechanisms

Determination of Activation Energy and Enthalpy

For the slow step in a reaction mechanism, the potential energy of the products is 110. kJ, the potential energy of the reactants is 80. kJ, and the potential energy of the transition state species is 200. kJ.

Draw a reaction profile for this elementary step.

What are the activation energies for the forward and reverse reactions?

What is the enthalpy for the forward reaction?

Video Solution

Determination of Activation Energy

For the elementary step, A ➞ Products, specific rate constants at two different temperatures were measured.

k (s-1)

T (˚C)

5.0

200.

10.0

400.

What is the activation energy (in kJ/mol) for this elementary step?

Video Solution

Determination of the Specific Rate Constant

For the elementary step, 2 X ➞ Products, the specific rate constant at 400. ˚C is 17. M-1s-1. If the activation energy for this elementary step is 37 kJ/mol, what is the specific rate constant at 100. ˚C?

Video Solution